You cannot access the Internet through a proxy server when you use a 32-bit version of Internet Explorer on a computer that is running a 64-bit version of Windows
Consider the following scenario. You are running a 32-bit version of Microsoft Internet Explorer on a computer that is running a 64-bit version of a Microsoft Windows operating system. You enable the Make proxy settings per-machine (rather than per-user) Group Policy settings. In this scenario, you cannot access the Internet through a proxy server.
For more information on this issue, including potential causes, workarounds, and resolutions, see: Microsoft KB Article KB952031.

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